Réaction #74963

ord-33984a9f0bc7469b92c1d7e96b01d0d9

Équation de réaction

ClC1=C(Cl)C(Cl)(Cl)C(Cl)=C1Cl
Hexachlorocyclopentadiene
CC(C)(C)C1=CC(=O)C=CC1=O
tert-butyl-p-benzoquinone
→
CC(C)(C)C1=CC(=O)C2C(C1=O)C1(Cl)C(Cl)=C(Cl)C2(Cl)C1(Cl)Cl
6-tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione

Réactifs

ClC1=C(Cl)C(Cl)(Cl)C(Cl)=C1Cl
Hexachlorocyclopentadiene
CC(C)(C)C1=CC(=O)C=CC1=O
tert-butyl-p-benzoquinone

Réactifs

Aucun

Solvants

Cc1ccccc1
toluene

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Traitement

  1. 1
    LavageThe solid was washed with methanol
  2. 2
    Autrerecrystallized from benzene
  3. 3
    AutreYellow crystals were obtained melting at 124°-125° C.

Mode opératoire

Hexachlorocyclopentadiene, 40 g., and 15.4 g. of tert-butyl-p-benzoquinone were dissolved in 300 ml. of toluene and refluxed for four hours. The solution solidified upon cooling to room temperature. The solid was washed with methanol and recrystallized from benzene. Yellow crystals were obtained melting at 124°-125° C.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US04174457uspto-grants-1979_11