Réaction #6668
ord-c7929215a1044905b53af2ac9d1a111e
Équation de réaction
CF3(CF2)9OCF(CF3)CF2OCOCF(CF3)OCF2CF2CF3
NaF
→
CF3(CF2)9OCF(CF3)COF
Rendement 63.8%
Réactifs
Aucun
Conditions de réaction
Température
150°CELSIUS
Conditions détaillées
See reaction.notes.procedure_details.
Traitement
- 1Autreadjusted to a temperature of 20° C.
- 2TempératureAfter cooling
- 3Autrethe liquid sample (1.9 g) was recovered
Mode opératoire
CF3(CF2)9OCF(CF3)CF2OCOCF(CF3)OCF2CF2CF3 (2.0 g) obtained in Example 23 was charged into a flask together with a NaF powder (0.05 g) and heated at 150° C. for 24 hours in an oil bath with vigorous stirring. At an upper part of the flask, a reflux condenser adjusted to a temperature of 20° C., was installed. After cooling, the liquid sample (1.9 g) was recovered. By GC-MS, it was confirmed that CF3CF(OCF2CF2CF3)COF and the above-identified compound were the main products. The yield was 63.8%.