Réaction #6543

ord-db48ca45905a4ffa943827bd251f129c

Équation de réaction

C1=CCCC1
cyclopentene
Cl[SiH](Cl)Cl
trichlorosilane
CC(C)O
isopropyl alcohol
→
Cl[Si](Cl)(Cl)C1CCCC1
Cyclopentyl trichlorosilane

Réactifs

C1=CCCC1
cyclopentene
Cl[SiH](Cl)Cl
trichlorosilane
CC(C)O
isopropyl alcohol

Réactifs

[Cl][Pt-2]([Cl])([Cl])([Cl])([Cl])[Cl].[H+].[H+]
chloroplatinic acid

Conditions de réaction

Température
150°CELSIUS
Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

In a 100 ml autoclave were charged 13.5 g (0.198 mole) of cyclopentene, 24.4 g (0.180 mole) of trichlorosilane and 25 μl of a 0.077 m mole/ml chloroplatinic acid solution in isopropyl alcohol (platinum content 1.92×10-6 mole), which were then stirred at 150° C. for 30 minutes. Cyclopentyl trichlorosilane was obtained quantitatively.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US05248803uspto-grants-1993_09