Réaction #6432
ord-e5f02821feab4e68bc5f37db01f810ce
Équation de réaction
Réactifs
Solvants
Conditions de réaction
Conditions détaillées
See reaction.notes.procedure_details.
Mode opératoire
A suspension containing two equivalents of sodium azide, one equivalent of the above-prepared iodonated oxaphosphorinane and a catalytic amount of about 0.1 equivalent of tetrabutylammonium bromide in benzene/DMF (1:1) was heated to 60-80 degrees C. for 16 hours to produce 2-phenoxy-2-oxo-6-(azidomethyl)-1,2-oxaphosphorinane in 96 percent yield as a white solid.