Réaction #638692

ord-029ee07459fc47be845ada8c010993b9

Équation de réaction

COc1cc(F)c(F)cc1-c1ccc(O)cc1
4′,5′-difluoro-2′-methoxy-biphenyl-4-ol
COc1cc(F)c(F)cc1-c1ccc(OCc2ccc3ccn(C(=O)OC(C)(C)C)c3c2)cc1
6-(4′,5′-difluoro-2′-methoxy-biphenyl-4-yloxymethyl)-indole-1-carboxylic acid tert-butyl ester
CC(C)(C)OC(=O)n1ccc2c(CO)cccc21
4-hydroxymethyl-indole-1-carboxylic acid tert-butyl ester
COc1cc(F)c(F)cc1-c1ccc(OCc2cccc3c2ccn3C(=O)OC(C)(C)C)cc1
4-(4′,5′-difluoro-2′-methoxy-biphenyl-4-yloxymethyl)-indole-1-carboxylic acid tert-butyl ester

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

4-(4′,5′-difluoro-2′-methoxy-biphenyl-4-yloxymethyl)-indole-1-carboxylic acid tert-butyl ester was synthesized by a procedure similar to 6-(4′,5′-difluoro-2′-methoxy-biphenyl-4-yloxymethyl)-indole-1-carboxylic acid tert-butyl ester from starting materials 4-hydroxymethyl-indole-1-carboxylic acid tert-butyl ester and 4′,5′-difluoro-2′-methoxy-biphenyl-4-ol to yield the product as a white solid (880 mg, 70%). LC-MS (ES) calculated for C27H25F2NO2, 465.2; found m/z 466 [M+H]+.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US07947728B1uspto-grants-2011_05