Réaction #566102

ord-fc1fcef7da60443da07a59caf901c296

Équation de réaction

CC(C)C12C=CC(C1)CC2(C(=O)[O-])C12CC3CC(CC(C3)C1)C2
1-adamantyl-1-methylethyl-5-norbornene-2-carboxylate
CC(C)C12C=CC(C1)CC2(C(=O)[O-])C12CC3CC(CC(C3)C1)C2
1-Adamanty-1-methylethyl-5-norbornene-2-carboxylate
O=C1C=CC(=O)O1
maleic anhydride
CC(C)(C#N)N=NC(C)(C)C#N
AIBN
→
CC(C)C12C=CC(C1)CC2(C(=O)[O-])C12CC3CC(CC(C3)C1)C2.O=C1C=CC(=O)O1
1-adamantyl-1-methylethyl-5-norbornene-2-carboxylate maleic Anhydride

Réactifs

CC(C)C12C=CC(C1)CC2(C(=O)[O-])C12CC3CC(CC(C3)C1)C2
1-adamantyl-1-methylethyl-5-norbornene-2-carboxylate
CC(C)C12C=CC(C1)CC2(C(=O)[O-])C12CC3CC(CC(C3)C1)C2
1-Adamanty-1-methylethyl-5-norbornene-2-carboxylate
O=C1C=CC(=O)O1
maleic anhydride
CC(C)(C#N)N=NC(C)(C)C#N
AIBN

Réactifs

Aucun

Solvants

C1CCOC1
THF

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Traitement

  1. 1
    Autredegassed
  2. 2
    Autrepolymerized at a temperature of about 65° C. for about 24 hours

Mode opératoire

10.8 g of 1-adamantyl-1-methylethyl-5-norbornene-2-carboxylate prepared in Example 1, and 3.37 g of maleic anhydride were dissolved in 7.1 9 of THF. 0.112 g of AIBN was added to the resultant, degassed and polymerized at a temperature of about 65° C. for about 24 hours.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US06642336B1uspto-grants-2003_11