Réaction #55601

ord-884dca2509ea4a878eebbc80f47f85a6

Équation de réaction

O=C(O)c1cc(Oc2ccc(C(F)(F)F)cc2Cl)ccc1[N+](=O)[O-]
5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoic acid
CC(C)(C)CC(C)(C)N
t-octylamine
→
CC(C)(C)CC(C)(C)[NH3+].O=C([O-])c1cc(Oc2ccc(C(F)(F)F)cc2Cl)ccc1[N+](=O)[O-]
product
Rendement 68.7%
CC(C)(C)CC(C)(C)[NH3+].O=C([O-])c1cc(Oc2ccc(C(F)(F)F)cc2Cl)ccc1[N+](=O)[O-]
t-Octylammonium 5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoate
Rendement 68.7%

Réactifs

O=C(O)c1cc(Oc2ccc(C(F)(F)F)cc2Cl)ccc1[N+](=O)[O-]
5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoic acid
CC(C)(C)CC(C)(C)N
t-octylamine

Réactifs

Aucun

Solvants

COCCOC
glyme

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Traitement

  1. 1
    AutreThe solvent is removed in vacuo
  2. 2
    Autrethe residue triturated with petroleum either (bp 30°-60° C.)
  3. 3
    Autredried

Mode opératoire

5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoic acid (3.0 g, 0.0083 mole) is dissolved in glyme (20 ml) and t-octylamine (1.17 g, 0.0091 mole) is added rapidly while stirring. The solvent is removed in vacuo and the residue triturated with petroleum either (bp 30°-60° C.) and dried to give 2.8 g of product, mp 140°-57° C.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US04220468uspto-grants-1980_09