Réaction #554586

ord-d4b8572a8f6a416bae269d076aed7805

Équation de réaction

CCCCC/C=C\C/C=C\CCCCCCCC(=O)OCC(O)CO
glyceryl monolinoleate
O=C1CCC(=O)O1
succinic anhydride
O=C1CCC(=O)O1
succinic anhydride
→
CCCCC/C=C\C/C=C\CCCCCCCC(=O)OCC(O)CO.O=C([O-])CCC(=O)[O-]
glyceryl monolinoleate succinate

Réactifs

CCCCC/C=C\C/C=C\CCCCCCCC(=O)OCC(O)CO
glyceryl monolinoleate
O=C1CCC(=O)O1
succinic anhydride
O=C1CCC(=O)O1
succinic anhydride

Réactifs

Aucun

Conditions de réaction

Température
140°CELSIUS
Conditions détaillées
See reaction.notes.procedure_details.

Traitement

  1. 1
    workup.ADDITIONwas added
  2. 2
    Autrea nitrogen inlet adapter was attached
  3. 3
    Autrewas placed into a room temperature
  4. 4
    Températurethe temperature was raised to 200° C
  5. 5
    TempératureHeat tape
  6. 6
    AutreThe flask was removed from the oil bath
  7. 7
    Températureto cool to room temperature

Mode opératoire

29.97 gm (84.6 mmoles) of glyceryl monolinoleate were added to a dry 100 ml, single neck, round bottom flask. A football stir bar was added and a nitrogen inlet adapter was attached. The reaction flask was placed into a room temperature oil bath and a nitrogen blanket was applied. The oil bath temperature was raised to 140° C. Once at 140° C., 8.47 gm (84.6 mmoles) succinic anhydride were added and the temperature was raised to 200° C. Heat tape was wrapped around the outside of the top of the flask and adapter to keep the succinic anhydride from subliming. The reaction was continued for 3 hours at 200° C. The flask was removed from the oil bath and allowed to cool to room temperature. The polymer was a pale yellow, viscous liquid.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08623413B2uspto-grants-2014_01