Réaction #54447

ord-4b0992e459a24daaa1b21148f6ab2d51

Équation de réaction

CCCCCCCCCCCCCCCCCC(=O)Cl
stearoyl chloride
ClCl
chlorine
O=S(=O)(O)Cl
ClSO3H
N#CC(C#N)=c1ccc(=C(C#N)C#N)cc1
TCNQ
→
CCCCCCCCCCCCCCCCC(Cl)C(=O)Cl
2-chlorostearoyl chloride

Réactifs

CCCCCCCCCCCCCCCCCC(=O)Cl
stearoyl chloride
ClCl
chlorine
O=S(=O)(O)Cl
ClSO3H
N#CC(C#N)=c1ccc(=C(C#N)C#N)cc1
TCNQ

Réactifs

Aucun

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Traitement

  1. 1
    workup.DISTILLATIONThe product is distilled

Mode opératoire

Following the procedure of Example I, stearoyl chloride is reacted with chlorine in the presence of ClSO3H and TCNQ. The product is distilled to provide substantially pure 2-chlorostearoyl chloride.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US04148811uspto-grants-1979_04