Réaction #5129

ord-62caf7e77d574b0eacf847ea9cbf3833

Équation de réaction

I.I.NC1=NCCCN1CCCCCCCCCCCCN1CCCN=C1N
1,12-bis(2-amino-3,4,5,6-tetrahydropyrimidyl)dodecane dihydroiodide
CO.O
methanol water
CC(=O)O.CC(=O)O.NC1=NCCCN1CCCCCCCCCCCCN1CCCN=C1N
guanidine
CC(=O)O.CC(=O)O.NC1=NCCCN1CCCCCCCCCCCCN1CCCN=C1N
1,12-Bis(2-amino-3,4,5,6-tetrahydropyrimidyl)dodecane diacetate

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

30.0 g (0.048 mol) of 1,12-bis(2-amino-3,4,5,6-tetrahydropyrimidyl)dodecane dihydroiodide in 300 ml of methanol/water (1:1) were filtered through a column containing 250 g of ion exchanger (OH- form). The free guanidine base obtained after working up was dissolved in methanol and converted into the diacetate with excess glacial acetic acid.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US05242948uspto-grants-1993_09