Réaction #502157

ord-4d5cd944bf294ca18178ce5ddc8a6cf8

Équation de réaction

CSc1nc(Cc2cccc(C(F)(F)F)c2)[nH]c(=O)c1C#N
4-(methylsulphanyl)-6-oxo-2-[3-(trifluoromethyl)benzyl]-1,6-dihydropyrimidine-5-carbonitrile
C1CCNCC1
piperidine
N#Cc1c(N2CCCCC2)nc(Cc2cccc(C(F)(F)F)c2)[nH]c1=O
title compound
N#Cc1c(N2CCCCC2)nc(Cc2cccc(C(F)(F)F)c2)[nH]c1=O
6-Oxo-4-(1-piperidinyl)-2-[3-(trifluoromethyl)benzyl]-1,6-dihydropyrimidine-5-carbonitrile

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

In analogy to the preparation of Example 1, 100 mg (0.31 mmol) of 4-(methylsulphanyl)-6-oxo-2-[3-(trifluoromethyl)benzyl]-1,6-dihydropyrimidine-5-carbonitrile are reacted with 262 mg (3.07 mmol) of piperidine to give 26 mg (22% of theory) of the title compound.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08088769B2uspto-grants-2012_01