Réaction #502156

ord-69f77c5ef71c46a1b19983c6214847db

Équation de réaction

CSc1nc(Cc2cccc(F)c2)[nH]c(=O)c1C#N
2-(3-fluorobenzyl)-4-(methylsulphanyl)-6-oxo-1,6-dihydropyrimidine-5-carbonitrile
C1CCNCC1
piperidine
N#Cc1c(N2CCCCC2)nc(Cc2cccc(F)c2)[nH]c1=O
title compound
N#Cc1c(N2CCCCC2)nc(Cc2cccc(F)c2)[nH]c1=O
2-(3-Fluorobenzyl)-6-oxo-4-(1-piperidinyl)-1,6-dihydropyrimidine-5-carbonitrile

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

In analogy to the preparation of Example 1, 100 mg (0.36 mmol) of 2-(3-fluorobenzyl)-4-(methylsulphanyl)-6-oxo-1,6-dihydropyrimidine-5-carbonitrile are reacted with 309 mg (3.63 mmol) of piperidine to give 40 mg (35% of theory) of the title compound.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08088769B2uspto-grants-2012_01