Réaction #502059

ord-11d94e99141441139220eea2e5013c4c

Équation de réaction

C/C(=C\CO)CCC[C@H](C)CCC[C@H](C)CCCC(C)C
phytol
[H][H]
hydrogen
→
CC(C)CCCC(C)CCCC(C)CCCC(C)CCO
phytanol

Réactifs

C/C(=C\CO)CCC[C@H](C)CCC[C@H](C)CCCC(C)C
phytol
[H][H]
hydrogen

Réactifs

[Ni]
Raney nickel

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

Hydrogenation of phytol can also be accomplished using Raney nickel and hydrogen to yield phytanol as referenced in Bendavid, A., Burns, C. J., Leslie, D. F., Hashimoto, K., Ridley, D. D., Sandanayake, S., and Wieczorek L., J. Org. Chem. (2001), 66, 3709-3716; Kim, T., Chan, K. C, and Crooks, R. M., J. Am. Chem. Soc. (1997) 119, 189; and Jellum, E., Eldjarn, L., and Try, K., Acta Chem. Scand. (1966), 20, 2335.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08088395B2uspto-grants-2012_01