Réaction #47136

ord-0ed1deefb693476d8324060234940cbd

Solvants

Conditions de réaction

Température
130°CELSIUS
Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

A mixture of 1.062 g (10 mmol) of ethylbenzene, 0.205 g (1 mmol) of N-acetoxyphthalimide, 0.025 g (0.1 mmol) of cobalt(II) acetate tetrahydrate, 0.025 g (0.1 mmol) of manganese(II) acetate tetrahydrate and 15 ml of acetic acid was stirred at 130° C. in an atmosphere of air [2 MPa (gauge pressure)] for 8 hours and thereby yielded benzoic acid in a yield of 85% (analyzed by gas chromatography) with a conversion from ethylbenzene of 96%. In this procedure, acetophenone was not produced.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US07741514B2uspto-grants-2010_06