Réaction #441164

Équation de réaction

sodium thiocyanate

N,N-diethyl carbamoyl chloride

→

N,N-Diethyl carbamoyl thiocyanate

Solvants

acetonitrile

acetonitrile

Conditions de réaction

Traitement

1. 1
   Températurecooled to room temperature
2. 2
   Filtrationfiltered through a fine glass frit

Mode opératoire

A suspension of sodium thiocyanate (3.30 g, 40.7 mmol) in dry acetonitrile (25 mL) at 80° C. was treated dropwise with a solution of N,N-diethyl carbamoyl chloride (5.0 g, 36.9 mmol) in dry acetonitrile (15 mL). The reaction mixture was stirred at 80° C. for 50 min, cooled to room temperature, then filtered through a fine glass frit. The resulting filtrate was used as a 0.9 M solution of N,N-diethyl carbamoyl thiocyanate in acetonitrile.

Source