Réaction #40301
ord-4a9b7976539f4e5b878d784e3b817458
Équation de réaction
4,4-dimethyl-cyclohex-2-enone
hydrogen
→
4,4-dimethyl-cyclohexanone
Rendement 94.0%
Réactifs
Solvants
Conditions de réaction
Conditions détaillées
See reaction.notes.procedure_details.
Traitement
- 1FiltrationFiltration over celite
- 2Concentrationconcentration
- 3Autreby evaporation
Mode opératoire
A solution of 4,4-dimethyl-cyclohex-2-enone (3 mmol) in ethyl acetate is hydrogenated overnight at room temperature using Pd/C (0.05 mmol) with hydrogen under normal pressure. Filtration over celite and then concentration by evaporation produces 4,4-dimethyl-cyclohexanone (355 mg) in a yield of 94% (J. Org. Chem. 2001, 66 (3), 733-738).