Réaction #2389085

Équation de réaction

9-Hydroxyphenalenone

aluminum chloride

→

Tris (9-oxidophenalenone) aluminum

Solvants

toluene

Conditions de réaction

Traitement

1. 1
   Autreto form
2. 2
   TempératureThe flask was then cooled
3. 3
   Filtrationthe contents filtered

Mode opératoire

9-Hydroxyphenalenone (1.5 g) was placed in a 100 mL round-bottom flask. Dry toluene (50 mL) was added to the flask together with aluminum chloride (0.113 g). The solution turned yellow-orange, and a precipitate began to form. The mixture was refluxed at 110° C. overnight. The flask was then cooled and the contents filtered. Crude yield 1.69 g, mp>300° C.

Source