Réaction #2358555

ord-9ad7a3c22fca468382d17d2abab2041b

Équation de réaction

OB(O)c1ccc2c3c(cccc13)-c1c-2c(-c2ccccc2)c2ccccc2c1-c1ccccc1
7,12-diphenylbenzo[k]fluoranthene-3-yl boronic acid
Brc1ccc2cc(Br)ccc2c1
2,6-dibromo-naphthalene
Brc1ccc2cc(-c3ccc4c5c(cccc35)-c3c-4c(-c4ccccc4)c4ccccc4c3-c3ccccc3)ccc2c1
3-(6-bromonaphthalen-2-yl)-7,12-diphenylbenzo[k]fluoranthene

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

It was carried out in a similar manner as Synthesis Example 1 except that 7,12-diphenylbenzo[k]fluoranthene-3-yl boronic acid was employed instead of 9,9-dimethyl-911-fluorene-2-yl boronic acid, and that 2,6-dibromo-naphthalene was employed instead of 3-bromo-7,12-dibenzo[k]fluoranthene in Synthesis Example 1 to obtain 3-(6-bromonaphthalen-2-yl)-7,12-diphenylbenzo[k]fluoranthene.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US09120748B2uspto-grants-2015_09