Réaction #2250934

Équation de réaction

ethanolamine

5-dodecyl-2-norbornene

1-hexene

diethylaluminum iodide

→

5-Dodecyl-2-Norbornene 1-Hexene

Solvants

benzene

Conditions de réaction

Traitement

1. 1
   Autrepurged 7 oz. bottle
2. 2
   workup.ADDITION0.75 ml of the MoCl5 solution was charged last
3. 3
   AutrePolymerization
4. 4
   AutreThe polymer was recovered
5. 5
   Filtrationfiltering
6. 6
   Autrevacuum drying

Mode opératoire

50 ml dry benzene cosolvent, 5 ml 5-dodecyl-2-norbornene, 2 ml of the 1-hexene solution and 0.6 ml of the diethylaluminum iodide solution were charged to a dry, nitrogen-purged 7 oz. bottle. 0.75 ml of the MoCl5 solution was charged last, and the bottle was shaken. Polymerization occurred rapidly, and after about 1 hour the reaction was shortstopped as usual with ethanolamine and Solution A. The polymer was recovered by coagulating, filtering, and vacuum drying and found to be a solid, ring-opened 5-dodecyl-2-norbornene/1-hexene copolymer having a DSV of about 1.23.

Source