Réaction #2204014

Équation de réaction

Water

toluene

N-[2-(2,3,4,5-tetramethylcyclopentadienyl)phenylmethylene]-N-(2,6-diisopropylphenyl)amine

sodium borohydride

→

N-[2-(2,3,4,5-tetramethylcyclopentadienyl)phenylmethyl]-N-(2,6-diisopropylphenyl)amine

Rendement 82.4%

Solvants

acetic acid

Conditions de réaction

Traitement

1. 1
   AutreThe mixture was reacted at room temperature for 1 hr
2. 2
   AutreThe organic layer was dried
3. 3
   Concentrationconcentrated
4. 4
   AutreThe obtained oily substance was purified by silica gel column chromatography

Mode opératoire

To a solution of N-[2-(2,3,4,5-tetramethylcyclopentadienyl)phenylmethylene]-N-(2,6-diisopropylphenyl)amine (10.0 mmol) in acetic acid (7.0 mL) was added sodium borohydride (13.0 mmol). The mixture was reacted at room temperature for 1 hr. Water and toluene were then added to the reaction mixture. The organic layer was dried and concentrated. The obtained oily substance was purified by silica gel column chromatography to give N-[2-(2,3,4,5-tetramethylcyclopentadienyl)phenylmethyl]-N-(2,6-diisopropylphenyl)amine (3.19 g, yield 82.4%) as a yellow oily substance.

Source