Réaction #2146717

Équation de réaction

ethylene carbonate

diethyl carbonate

2,2′-azobis(isobutyronitrile)

methyl methacrylate

3-ethyl-3-oxetanylmethyl methacrylate

3,4-epoxycyclohexylmethyl acrylate

→

ethylene carbonate diethyl carbonate

Conditions de réaction

Traitement

1. 1
   Autreequipped with a refluxing condenser
2. 2
   workup.ADDITIONmixed for 30 minutes while nitrogen gas
3. 3
   workup.ADDITIONwas introduced into the flask
4. 4
   Autreradical polymerization
5. 5
   AutreThe resulting reaction mixture
6. 6
   Températurewas cooled to 40° C
7. 7
   Températurethe resulting mixture was again heated to 70° C.
8. 8
   Autrepolymerization at the temperature for another 8 hours
9. 9
   AutreThen the resulting reaction mixture
10. 10
    Températurewas cooled to 40° C.

Mode opératoire

60.0 g of methyl methacrylate, 16.0 g of 3-ethyl-3-oxetanylmethyl methacrylate, 4.0 g of 3,4-epoxycyclohexylmethyl acrylate, 226.6 g of ethylene carbonate and 0.15 g N,N′-azobis(isobutyronitrile) were placed in a 500 Ml Capacity three-necked flask equipped with a refluxing condenser, and stirred and mixed for 30 minutes while nitrogen gas was introduced into the flask. Then the resulting mixture was heated to 70° C. and radical polymerization was carried out over 8 hours at the temperature. The resulting reaction mixture was cooled to 40° C. 226.6 g of diethyl carbonate and 0.15 g of 2,2′-azobis(isobutyronitrile) were added to the reaction mixture and the resulting mixture was again heated to 70° C. to carry out radical polymerization at the temperature for another 8 hours. Then the resulting reaction mixture was cooled to 40° C. to obtain a solution of a polymer in a concentration of 15% by weight in a solvent of ethylene carbonate/diethyl carbonate mixture.

Source