Réaction #2128978

ord-1a1da7179e2b4f4a9ac7f6b9129a1f23

Équation de réaction

Cc1c([N+](=O)[O-])cc([N+](=O)[O-])cc1[N+](=O)[O-]
TNT
O=[N+]([O-])OCC(CO[N+](=O)[O-])(CO[N+](=O)[O-])CO[N+](=O)[O-]
PETN
→
Cc1c([N+](=O)[O-])cc([N+](=O)[O-])cc1[N+](=O)[O-].O=[N+]([O-])OCC(CO[N+](=O)[O-])(CO[N+](=O)[O-])CO[N+](=O)[O-]
PETN TNT

Réactifs

Cc1c([N+](=O)[O-])cc([N+](=O)[O-])cc1[N+](=O)[O-]
TNT
O=[N+]([O-])OCC(CO[N+](=O)[O-])(CO[N+](=O)[O-])CO[N+](=O)[O-]
PETN
—
xanthan gum

Réactifs

Aucun

Conditions de réaction

Température
95°CELSIUS
Conditions détaillées
See reaction.notes.procedure_details.

Traitement

  1. 1
    Autreuntil melting in a reactor
  2. 2
    Autreprovided with a heating jacket and with mechanical stifling
  3. 3
    workup.ADDITIONwas poured on a cylindrical mold
  4. 4
    workup.WAITleft
  5. 5
    Températureto cool, in order

Mode opératoire

Briefly, a quantity of TNT were added and heated at 95° C. until melting in a reactor provided with a heating jacket and with mechanical stifling. Then, a quantity of PETN were added with a quantity of a gum [e.g., xanthan gum or guar gum] and a quantity of a wax. The components were stirred until achieving a homogeneous mixture which was poured on a cylindrical mold and left to cool, in order to obtain a composition of PETN/TNT/gum/wax with the desired percentage. The cylinders thus obtained are submersed in water at room temperature (18-22° C.) and the effect obtained on the integrity of the cylinder is determined at different times. More information can be found on Example 14].

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08585841B2uspto-grants-2013_11