Réaction #2075705

Équation de réaction

Glycerol

sebacic acid

→

glycerol sebacate

Solvants

toluene

Conditions de réaction

Traitement

1. 1
   workup.DISSOLUTIONdissolved
2. 2
   workup.ADDITIONAfter an enzyme B (5 wt %) was added as a catalyst
3. 3
   Autreto react at 100° C. for 72 hours
4. 4
   AutreThe resulting product was dried for 24 hours at reduced pressure

Mode opératoire

Glycerol (0.2 mol) was added to 30 ml of toluene containing sebacic acid (0.2 mol) dissolved therein, and then stirred in an argon atmosphere at 55° C. for one hour. After an enzyme B (5 wt %) was added as a catalyst, the mixture was allowed to react at 100° C. for 72 hours. Polycondensation was carried out using a dean-stark trap device. The resulting product was dried for 24 hours at reduced pressure.

Source