Réaction #2028925

ord-9f418bbc4fbe49e19dc7f904031fa364

Équation de réaction

C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)CO
6-deoxy L-mannitol
C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)CO
6-deoxy L-mannitol
C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)C=O
6-deoxy L-mannose
→
C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)CO
6-deoxy L-mannitol
CC(=O)[C@H](O)[C@@H](O)[C@@H](O)CO
1-deoxy L-fructose
C[C@H](O)[C@H](O)[C@@H](O)C(=O)CO
6-deoxy L-fructose

Réactifs

C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)CO
6-deoxy L-mannitol
C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)CO
6-deoxy L-mannitol
C[C@H](O)[C@H](O)[C@@H](O)[C@@H](O)C=O
6-deoxy L-mannose

Réactifs

Aucun

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

6-Deoxy L-mannitol can readily be produced via chemical reduction of 6-deoxy L-mannose. At a productivity close to 99%, 6-deoxy L-mannose is completely converted to 6-deoxy L-mannitol. When the initial concentrations of 6-deoxy L-mannitol were 3%, 4% and 5%, almost 90%, 70% and 65%, respectively of 6-deoxy L-mannitol produced 6-deoxy L-fructose and 1-deoxy L-fructose, using the washed bacterial cell reaction.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08389248B2uspto-grants-2013_03