Réaction #1960516

ord-1ce217c034a24955a38896e73a92e6af

Équation de réaction

[Zn]
Zn
O=[PH2]O
H3PO2
O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Zn+2]
zinc nitrate hexahydrate
→
O=P([O-])([O-])[O-].O=P([O-])([O-])[O-].[Zn+2].[Zn+2].[Zn+2]
Zinc Phosphate

Réactifs

[Zn]
Zn
O=[PH2]O
H3PO2
O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Zn+2]
zinc nitrate hexahydrate
—
Zn(NO3)2.6H2O
—
Zn3(PO4)2

Réactifs

Aucun

Solvants

O
water

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Traitement

  1. 1
    Autreto form a clear, colorless solution

Mode opératoire

An aqueous solution of 13.67 g 50 wt % H3PO2 was combined with 5.00 g deionized water to form a clear, colorless solution contained in a 250 ml Pyrex beaker. To this solution was added 46.23 g zinc nitrate hexahydrate salt, Zn(NO3)2.6H2O (Aldrich Chemical Co., Inc. #22, 873-7, CAS #10196-18-6), equivalent to 21.97 wt. % Zn. The molar ratio of [Zn]2+/[PO4]−3 in this mixture was 3/2 and the equivalent solids level [as Zn3(PO4)2] was 27.5 wt. %.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08303976B2uspto-grants-2012_11