Réaction #1797484

Équation de réaction

phthalic acid

KOH

→

Mono-n-butylphthalic Acid

Solvants

n-butyl alcohol

Conditions de réaction

Traitement

1. 1
   Autreequipped with stirring blades
2. 2
   Températurethermometer and Dimroth condenser, heated
3. 3
   Températureraised to a temperature of 130° C., which
4. 4
   Températurewas maintained for 2 hours
5. 5
   TempératureThe mixture was subsequently cooled to 60° C

Mode opératoire

148.2 g of anhydrous phthalic acid and 1.05 times the molar equivalent 77.8 g of n-butyl alcohol were added to a 500 ml glass round-bottomed flask equipped with stirring blades, thermometer and Dimroth condenser, heated while slowly stirring, and after the generated heat at about 90° C. wore off, raised to a temperature of 130° C., which was maintained for 2 hours. The mixture was subsequently cooled to 60° C. The acid value (number of mg of KOH necessary to neutralize 1 g of a sample) of the reaction solution was 253.8. Since the acid value for the case where the reaction is 100% complete is 248.4, the reaction rate was computed to be 98%.

Source