Réaction #1747856

ord-2b83896897a3434c9ae4badf2eb8a0e4

Équation de réaction

CN1c2ccc(-c3cccc4ccccc34)cc2S(=O)c2cc(-c3cccc4ccccc34)ccc21
10-methyl-3,7-bis(1-naphthyl)phenothiazine 5-oxide
O=C(OO)c1cccc(Cl)c1
m-chloroperbenzoic acid
CN1c2ccc(-c3cccc4ccccc34)cc2S(=O)(=O)c2cc(-c3cccc4ccccc34)ccc21
10-Methyl-3,7-bis(1-naphthyl)phenothiazine 5,5-dioxide

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Traitement

  1. 1
    AutreFor the preparation as a by-product

Mode opératoire

For the preparation as a by-product in the synthesis of 10-methyl-3,7-bis(1-naphthyl)phenothiazine 5-oxide, see under Example 5. For a selective preparation of the sulfone, at least two molar equivalents of m-chloroperbenzoic acid are used.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08029919B2uspto-grants-2011_10