Réaction #1563881

Équation de réaction

p-Toluene sulfonic acid

Iodine

m-CPBA

thiophene

→

dithienyliodonium tosylate

Rendement 11.2%

Solvants

dichloromethane

Conditions de réaction

Traitement

1. 1
   AutreThe solution was evaporated to dryness

Mode opératoire

Iodine (862 mg, 3.39 mmol), m-CPBA (1.48 g, 8.62 mmol) and thiophene (1 g. 11.88 mmol) were combined in dry dichloromethane (66 mL). p-Toluene sulfonic acid (2.19 g, 11.56 mmol) was added to the solution at room temperature, and the mixture was stirred for 16 hours at room temperature. The solution was evaporated to dryness, and the resulting crude product was subjected to flash chromatography (5-10% MeOH/CH2Cl2)) to yield dithienyliodonium tosylate (11.2%) as a brown colored sticky mass.

Source