Réaction #1473036

ord-85de58f66ddc43c29b946c8b4aa54e18

Équation de réaction

C[N+](C)(C)C.[OH-]
tetramethylammonium hydroxide
O=S(=O)(Cl)c1c(F)c(F)c(F)c(F)c1F
pentafluorobenzenesulfonyl chloride
C[N+](C)(C)C.O=S(=O)([O-])c1c(F)c(F)c(F)c(F)c1F
tetramethylammonium pentafluorobenzenesulfonate

Solvants

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

In 100 ml of methanol, 25 g of pentafluorobenzenesulfonyl chloride was dissolved under ice cooling, and 100 g of a 25% aqueous solution of tetramethylammonium hydroxide was slowly added thereto. Stirring at room temperature for 3 hours provided a solution of tetramethylammonium pentafluorobenzenesulfonate. This solution was used for salt exchange with a sulfonium salt and an iodonium salt.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US06265135B1uspto-grants-2001_07