Réaction #1458414

Équation de réaction

tetraphenylcyclopentadienone

isobutylamine

diethyl ether

→

title compound

Rendement 67.1%

N-isobutyl-2,3,4,5-tetraphenylcyclopentadieneimine

Rendement 67.1%

Solvants

toluene

Conditions de réaction

Traitement

1. 1
   Autreat 0° C
2. 2
   Températurerefluxed for 12 hours
3. 3
   TempératureThe reaction mixture was cooled
4. 4
   Autresolid precipitation
5. 5
   FiltrationThe resultant solid was filtered
6. 6
   Autredried

Mode opératoire

3 g (7.8 mmol) of tetraphenylcyclopentadienone and 3.49 ml (35.1 mmol) of isobutylamine were dissolved in 50 ml of toluene and 0.7 ml (5.85 mmol) of TiCl4 was added thereto at 0° C. The resulting mixture was agitated for 30 minutes at room temperature and then refluxed for 12 hours. The reaction mixture was cooled and diethyl ether was added thereto to induce solid precipitation. The resultant solid was filtered and dried to obtain 2.3 g of the title compound.

Source