Réaction #1340568

Équation de réaction

azobisisobutyronitrile

p-t-butoxystyrene

p-hydroxystyrene

sulfuric acid

divinylbenzene

p-t-butoxystyrene

styrene

→

divinylbenzene p-hydroxystyrene styrene

Solvants

ethyl acetate

propylene glycol monomethyl ether

Conditions de réaction

Traitement

1. 1
   Autrethe components were reacted at 90° C. for 10 hours
2. 2
   Lavagethe mixture was washed five times with water
3. 3
   AutreAfter isolating the ethyl acetate phase
4. 4
   Autrethe solvent was removed

Mode opératoire

1 part by mass of divinylbenzene (manufactured by Nippon Steel Chemical Co., Ltd., purity: 57 mass %), 60 parts by mass of p-t-butoxystyrene, and 4 parts by mass of styrene were dissolved in 150 parts by mass of propylene glycol monomethyl ether. The mixture was polymerized at 70° C. for 10 hours in a nitrogen atmosphere in the presence of 4 parts by mass of azobisisobutyronitrile. After the addition of sulfuric acid to the reaction solution, the components were reacted at 90° C. for 10 hours to convert (deprotect) p-t-butoxystyrene to p-hydroxystyrene. After the addition of ethyl acetate to the resulting copolymer, the mixture was washed five times with water. After isolating the ethyl acetate phase, the solvent was removed to obtain a divinylbenzene/p-hydroxystyrene/styrene copolymer (hereinafter referred to as “resin (A-1)”). The resin (A-1) was analyzed by 13C-NMR. The resin (A-1) had a content of the structural unit (a1-1) derived from divinylbenzene of 1 mol %, a content of the structural unit (a2) derived from p-hydroxystyrene of 89 mol %, and a content of the structural unit (a3-1) derived from styrene of 10 mol %. The resin (A-1) had a polystyrene-reduced weight average molecular weight of 24,000.

Source