Réaction #1256745

ord-844775fd74eb46848986d4a150b8bd07

Équation de réaction

CC(C)C[SiH](C(C)C)C(C)C
Compound 40a
CC(C)C[SiH](C(C)C)C(C)C
Isobutyldiisopropylsilane
CC(C)[SiH](Cl)C(C)C
diisopropylchlorosilane
→
CC(C)[SiH](C(C)C)C1CC1
Compound 44a
CC(C)[SiH](C(C)C)C1CC1
Cyclopropyldiisopropylsilane

Réactifs

CC(C)C[SiH](C(C)C)C(C)C
Compound 40a
CC(C)C[SiH](C(C)C)C(C)C
Isobutyldiisopropylsilane
CC(C)[SiH](Cl)C(C)C
diisopropylchlorosilane

Réactifs

Aucun

Solvants

—
cyclopropylmagnesium bromide THF

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

The procedure of synthesizing Compound 40a was repeated, except that diisopropylchlorosilane (4.10 mL, 96.0 mmol) and cyclopropylmagnesium bromide THF solution (1.0M, 100 mL) were employed, whereby the Compound 44a was obtained as a colorless liquid (boiling point; 35 mmHg, 86 to 89° C. fraction, 1.84 g, 50%).

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US07825103B2uspto-grants-2010_11