Réaction #1121763

ord-f3df3446cb8943d982e62deae0be4fec

Équation de réaction

COC(=O)c1c2ccccc2[n+](C)c2ccccc12.O=S(=O)([O-])C(F)(F)F
methyl 10-methylacridinium-9-carboxylate trifluoromethanesulfonate
→
COC(=O)C1c2ccccc2N(C)c2ccccc21
methyl 10-methylacridan-9-carboxylate

Réactifs

COC(=O)c1c2ccccc2[n+](C)c2ccccc12.O=S(=O)([O-])C(F)(F)F
methyl 10-methylacridinium-9-carboxylate trifluoromethanesulfonate

Réactifs

Aucun

Solvants

CO
methanol

Conditions de réaction

Conditions détaillées
See reaction.notes.procedure_details.

Mode opératoire

A solution of methyl 10-methylacridinium-9-carboxylate trifluoromethanesulfonate (75), 4.25 parts, in methanol is reduced as described in Example I to give 3.2 parts of methyl 10-methylacridan-9-carboxylate and the isolated product has the following structure confirmed by NMR.

Source

DOI: 10.6084/m9.figshare.5104873.v1Brevet: US08546150B2uspto-grants-2013_10