Réaction #1074082
ord-bedb0cfb051b4c12b5983b7c751f2b97
Équation de réaction
pentafluorobenzenesulfonyl chloride
tetramethylammonium hydroxide
→
tetramethylammonium pentafluorobenzene sulfonate
Réactifs
Aucun
Solvants
Conditions de réaction
Conditions détaillées
See reaction.notes.procedure_details.
Mode opératoire
25 g of pentafluorobenzenesulfonyl chloride was dissolved in 100 ml of methanol under ice cooling and thereto, 100 g of a 25% aqueous tetramethylammonium hydroxide solution was gradually added. The resulting solution was stirred at room temperature for 3 hours, then, a solution of tetramethylammonium pentafluorobenzene sulfonate was obtained. This solution was used for the salt exchange with sulfonium salt or iodonium salt. 2) Synthesis of Di(4-t-Amylphenyl)iodonium Pentafluorobenzene Sulfonate (D-4)