Reacción #992696

ord-4f35ba68c5da457ab8339458b719f25e

Ecuación de reacción

O=C/C(Br)=C(/Br)C(=O)O
Mucobromic acid
N=C(N)NN.O=C(O)O
Aminoguanidine bicarbonate
O=C=O
carbon dioxide
→
NNC(N)=[NH2+].O=C/C(Br)=C(/Br)C(=O)[O-]
Aminoguanidinium Mucobromate

Reactantes

O=C/C(Br)=C(/Br)C(=O)O
Mucobromic acid
N=C(N)NN.O=C(O)O
Aminoguanidine bicarbonate
O=C=O
carbon dioxide

Reactivos

Ninguno

Disolventes

O
water

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    OtroThe water was removed in vacuo
  2. 2
    Temperaturawith heating to approximately 90° C
  3. 3
    OtroThe product was isolated as an off-white solid

Procedimiento

Mucobromic acid (2.0 g, 7.76 mmol) was dissolved in 10 ml of distilled water. Aminoguanidine bicarbonate (1.06 g, 7.76 mmol) was added in portions at room temperature (carbon dioxide gas was evolved) and the reaction was stirred at room temperature for 18 hours. The water was removed in vacuo with heating to approximately 90° C. The product was isolated as an off-white solid.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US08012277B2uspto-grants-2011_09