Reacción #94253

Ecuación de reacción

1,3-dimethyl-3(t-butylperoxy)butyl chloroformate

dimethylamine

→

1,3-Dimethyl-3-(t-butylperoxy)butyl N,N-dimethylcarbamate

Disolventes

diethyl ether

diethyl ether

Condiciones de reacción

Tratamiento posterior

1. 1
   workup.ADDITIONAfter the addition
2. 2
   Otroto rise to 20°±1° C
3. 3
   FiltraciónThe reaction mixture was then filtered
4. 4
   Otroto remove the amine hydrochloride
5. 5
   Lavadothe organic phase washed with 10% aqueous Tartaric acid solution and water to neutrality

Procedimiento

To a solution of (97%) 1,3-dimethyl-3(t-butylperoxy)butyl chloroformate 5.2 g. (0.02 mole) in diethyl ether, cooled to 0°±1° C was added a solution of dimethylamine, 1.8 g. (0.04 mole) in diethyl ether over a period of 10 minutes. After the addition was complete the mixture was allowed to stir for two hours while the reaction temperature was allowed to rise to 20°±1° C. The reaction mixture was then filtered to remove the amine hydrochloride and the organic phase washed with 10% aqueous Tartaric acid solution and water to neutrality.

Fuente