Reacción #91323

ord-0bd1d95c328c427793bf4c5df71f66a9

Ecuación de reacción

NCc1ccc(Oc2ccccc2)cc1
4-phenoxybenzylamine
O=C(O)c1ccncc1F
3-fluoroisonicotinic acid
O=C(O)c1ccncc1NCc1ccc(Oc2ccccc2)cc1
title compound
Rendimiento 36.0%
O=C(O)c1ccncc1NCc1ccc(Oc2ccccc2)cc1
3-[(4-phenoxybenzyl)amino]pyridine-4-carboxylic acid
Rendimiento 36.0%

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

The title compound was prepared in 36% yield from 4-phenoxybenzylamine and 3-fluoroisonicotinic acid according to the procedure for the preparation of Example 3. 1H NMR (400 MHz, DMSO-d6): δ 13.42 (br s, 1H), 8.18 (s, 1H), 7.83 (d, 1H, J=5.0 Hz), 7.57 (d, 1H, J=5.0 Hz), 7.35-7.40 (m, 4H), 7.13 (t, 1H, J=7.2), 6.97-7.02 (m, 4H), 4.55 (s, 2H). [M+H] calc'd for C19H16N2O3, 321. found 321.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US09447045B2uspto-grants-2016_09