Reacción #91317

ord-8800806044b842208011b910053aeecd

Ecuación de reacción

NCc1ccc(C(F)(F)F)cc1
4-(trifluoromethyl)-benzylamine
O=C(O)c1ccncc1F
3-fluoroisonicotinic acid
O=C(O)c1ccncc1NCc1ccc(C(F)(F)F)cc1
title compound
Rendimiento 28.0%
O=C(O)c1ccncc1NCc1ccc(C(F)(F)F)cc1
3-{[4-(trifluoromethyl)benzyl]amino}pyridine-4-carboxylic acid
Rendimiento 28.0%

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

The title compound was prepared in 28% yield from 4-(trifluoromethyl)-benzylamine and 3-fluoroisonicotinic acid according to the procedure for the preparation of Example 3. 1H NMR (400 MHz, DMSO-d6): δ 8.10 (br s, 1H), 8.04 (s, 1H), 7.83 (d, 1H, J=5.0 Hz), 7.81 (d, 2H, J=8.0 Hz), 7.58 (d, 1H, J=5.0 Hz), 7.54 (d, 2H, J=8.0 Hz), 4.69 (s, 2H). [M+H] calc'd for C14H11F3N2O2, 297. found 297.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US09447045B2uspto-grants-2016_09