Reacción #75019

ord-b1b112f817fe40b399d7745d85d5634b

Ecuación de reacción

C=CCCCCCC
Octene-1
CC(=O)[O-].[K+]
potassium acetate
→
CCCCCCC1CCC(=O)O1
gamma-n-hexyl butyrolactone
Rendimiento 31.0%

Reactantes

—
ceric acetate
C=CCCCCCC
Octene-1
CC(=O)[O-].[K+]
potassium acetate

Reactivos

Ninguno

Disolventes

CC(=O)O
acetic acid

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

Octene-1 in an amount of 2.2 grams and 23.6 grams of ceric acetate were refluxed under nitrogen in 200 milliliters of glacial acetic acid containing 60 grams of potassium acetate for less than 0.4 hour, there being obtained a 31% yield of gamma-n-hexyl butyrolactone.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US04175089uspto-grants-1979_11