Reacción #74963

Ecuación de reacción

Hexachlorocyclopentadiene

tert-butyl-p-benzoquinone

→

6-tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione

Disolventes

toluene

Condiciones de reacción

Tratamiento posterior

1. 1
   LavadoThe solid was washed with methanol
2. 2
   Otrorecrystallized from benzene
3. 3
   OtroYellow crystals were obtained melting at 124°-125° C.

Procedimiento

Hexachlorocyclopentadiene, 40 g., and 15.4 g. of tert-butyl-p-benzoquinone were dissolved in 300 ml. of toluene and refluxed for four hours. The solution solidified upon cooling to room temperature. The solid was washed with methanol and recrystallized from benzene. Yellow crystals were obtained melting at 124°-125° C.

Fuente