Reacción #710461

ord-e4ad890d40d44f70a28960b2754401a0

Ecuación de reacción

COC(=O)c1cc(Br)cc(C)c1N
2-amino-3-methyl 5-bromobenzoic acid methyl ester
CCN(CC)CCN
N,N-diethyl ethylenediamine
CCN(CC)CCNC(=O)c1cc(Br)cc(C)c1N
N-diethylaminoethyl-2-amino-3-methyl-5-bromobenzamide
Rendimiento 84.2%

Disolventes

Condiciones de reacción

Temperatura
78°CELSIUS
Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    Otroreacted for 4 hours

Procedimiento

To a 100 mL round-bottom flask, 0.1 mol of 2-amino-3-methyl 5-bromobenzoic acid methyl ester having the structural formula of VIII-2, 100 mL of ethanol, 0.3 mol of N,N-diethyl ethylenediamine were added, heated to 78° C. and reacted for 4 hours, after treatment 27.5 grams of N-diethylaminoethyl-2-amino-3-methyl-5-bromobenzamide having a structural formula of III-2 was obtained, and the yield was 84.2%;

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US09301529B2uspto-grants-2016_04