Reacción #651864

ord-619dddc516084022b85e8f2c0b3b2efb

Ecuación de reacción

C=C(C)C(=O)OC(C)(C)C
tert-butyl methacrylate
C=C(C)C(=O)Oc1ccc2ccccc2c1
2-naphthyl methacrylate
CC(C)(C#N)N=NC(C)(C)C#N
AIBN
→
C=C(C)C(=O)Oc1cccc2ccccc12
naphthyl methacrylate
C=C(C)C(=O)OC(C)(C)C
Resin A
C=C(C)C(=O)OC(C)(C)C
tert-butyl methacrylate

Reactantes

C=C(C)C(=O)OC(C)(C)C
tert-butyl methacrylate
C=C(C)C(=O)Oc1ccc2ccccc2c1
2-naphthyl methacrylate
CC(C)(C#N)N=NC(C)(C)C#N
AIBN

Reactivos

Ninguno

Disolventes

Cc1ccccc1
toluene

Condiciones de reacción

Temperatura
70°CELSIUS
Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    workup.ADDITIONwas added
  2. 2
    Otropurified

Procedimiento

0.3 mol of 2-naphthyl methacrylate and 0.7 mol of tert-butyl methacrylate were mixed with 200 g of toluene, and 2 g of azoisobutylonitrile (AIBN) was added thereto. The mixed system was heated at a temperature of 70° C. for 8 hours and then purified by dropping it into acetone-methanol solvent, to obtain a copolymer of naphthyl methacrylate and tert-butyl methacrylate (Resin A).

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US06168897Auspto-grants-2001_01