Reacción #64335

Ecuación de reacción

dimethyl 1,1-cyclohexanedicarboxylate

aluminum oxide

→

methyl cyclohexanecarboxylate

Disolventes

methanol

Condiciones de reacción

Tratamiento posterior

1. 1
   OtroThe exit mixture obtained over 6 hours (36.5 g)
2. 2
   workup.DISTILLATIONwas distilled

Procedimiento

Per hour a solution of 4.5 g of dimethyl 1,1-cyclohexanedicarboxylate in 4.5 g of methanol was passed at 275° C. over 5 g of aluminum oxide. The exit mixture obtained over 6 hours (36.5 g) was distilled to yield 10.1 g of methyl cyclohexanecarboxylate (53%, based on diester used) and 7.7 g of the starting material.

Fuente