Reacción #62970

ord-01f407b26c404daab6db59143a8e4364

Ecuación de reacción

OCC(O)CBr
bromomethyl ethylene glycol
O=S(=O)([O-])[O-].[Mg+2]
magnesium sulfate
CC(C)=O
acetone
→
CC1(C)OCC(CBr)O1
crude product
CC1(C)OCC(CBr)O1
2,2-Dimethyl-4-bromomethyl-1,3-dioxolane

Reactantes

OCC(O)CBr
bromomethyl ethylene glycol
O=S(=O)([O-])[O-].[Mg+2]
magnesium sulfate
CC(C)=O
acetone

Reactivos

Ninguno

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    OtroThe cooled reaction mixture
  2. 2
    Filtraciónis filtered
  3. 3
    Otrothe solvent is removed

Procedimiento

An acetone solution of bromomethyl ethylene glycol is refluxed for 24 hours in the presence of anhydrous magnesium sulfate. The cooled reaction mixture is filtered and the solvent is removed to provide a residual crude product.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US04762912uspto-grants-1988_08