Reacción #6160

ord-33bd20993ae242758a05ade7c8cf3ad4

Ecuación de reacción

C=CCC[C@@H](O)C[C@@H]1OC(=O)[C@H]1CCCCCCCCCC
(S)-3-decyl-(S)-4-[(R)-2-hydroxy-5-hexenyl)-2-oxetanone
CC(C)C[C@H](NC=O)C(=O)O
N-formyl-L-leucine
→
CCCCCCC/C=C\CC[C@@H](C[C@@H]1OC(=O)[C@H]1CCCCCC)OC(=O)[C@H](CC(C)C)NC=O
N-formyl-L-leucine (S,Z)-1-[[(2S,3S)-3-hexyl-4-oxo-2-oxetanyl]methyl]-4-dodecenyl ester

Reactantes

C=CCC[C@@H](O)C[C@@H]1OC(=O)[C@H]1CCCCCCCCCC
(S)-3-decyl-(S)-4-[(R)-2-hydroxy-5-hexenyl)-2-oxetanone
CC(C)C[C@H](NC=O)C(=O)O
N-formyl-L-leucine

Reactivos

Ninguno

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    Otrothere was obtained

Procedimiento

by esterifying (S)-3-decyl-(S)-4-[(R)-2-hydroxy-5-hexenyl)-2-oxetanone with N-formyl-L-leucine there was obtained

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US05246960uspto-grants-1993_09