Reacción #586085

Ecuación de reacción

KCl

1-Butyl-3-methylimidazolium chloride

potassium 1,1,2-trifluoro-2-(perfluoroethoxy)ethanesulfonate

→

product

Rendimiento 62.0%

1-butyl-3-methylimidazolium 1,1,2-trifluoro-2-(perfluoroethoxy)ethanesulfonate

Rendimiento 62.0%

Disolventes

acetone

acetone

Condiciones de reacción

Tratamiento posterior

1. 1
   Otroto settle leaving a colorless solution above it
2. 2
   FiltraciónThe reaction mixture was filtered once through a celite/acetone pad
3. 3
   Otroagain through a fritted glass funnel to remove the KCl
4. 4
   OtroThe acetone was removed in vacuo first on a rotovap
5. 5
   workup.WAITon a high vacuum line (4 Pa, 25 degrees C.) for 2 hr
6. 6
   OtroResidual KCl was still precipitating out of the solution, so methylene chloride (50 ml)
7. 7
   workup.ADDITIONwas added to the crude product, which
8. 8
   Lavadowas then washed with deionized water (2×50 ml)
9. 9
   SecadoThe solution was dried over magnesium sulfate
10. 10
    Otrothe solvent was removed in vacuo

Procedimiento

1-Butyl-3-methylimidazolium chloride (Bmim-Cl, 7.8 g) and dry acetone (150 ml) were combined at room temperature in a 500 ml flask. At room temperature in a separate 200 ml flask, potassium 1,1,2-trifluoro-2-(perfluoroethoxy)ethanesulfonate (TPES-K, 15.0 g) was dissolved in dry acetone (300 ml). These two solutions were combined and allowed to stir magnetically for 12 hr under positive nitrogen pressure. The KCl precipitate was then allowed to settle leaving a colorless solution above it. The reaction mixture was filtered once through a celite/acetone pad and again through a fritted glass funnel to remove the KCl. The acetone was removed in vacuo first on a rotovap and then on a high vacuum line (4 Pa, 25 degrees C.) for 2 hr. Residual KCl was still precipitating out of the solution, so methylene chloride (50 ml) was added to the crude product, which was then washed with deionized water (2×50 ml). The solution was dried over magnesium sulfate, and the solvent was removed in vacuo to give the product as a viscous light yellow oil (12.0 g, 62% yield).

Fuente