Reacción #565258

ord-3f6f4f62c9f14855a8983544f3155d68

Ecuación de reacción

C=CC(=O)CC
ethyl vinyl ketone
CCOC(=O)C1CCC(=O)C=C1C
Hagemann's ester
C=C(C)C1CC=C(C)C(=O)C1
carvone
CCOC(=O)CCCl
ethyl 3-chloropropionate
→
CCOC(=O)C12CCC(=O)C=C1C=C(O)CC2
4a-Carboethoxy-7-hydroxy-4,4a,5,6-tetrahydro-2(3H)-naphthalenone

Reactantes

C=CC(=O)CC
ethyl vinyl ketone
CCOC(=O)C1CCC(=O)C=C1C
Hagemann's ester
C=C(C)C1CC=C(C)C(=O)C1
carvone
CCOC(=O)CCCl
ethyl 3-chloropropionate

Reactivos

Ninguno

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    OtroThis material is prepared

Procedimiento

This material is prepared according to the procedure for Preparation 6 wherein Hagemann's ester (ethyl 2-methyl-4-oxocyclohex-2-enyl-1-carboxylate) is substituted for carvone and ethyl 3-chloropropionate is substituted for ethyl vinyl ketone.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US04889947uspto-grants-1989_12