Reacción #55931

ord-1edbd020e7a4426484b3cc59f9886857

Ecuación de reacción

O=C1C=CC(=O)O1
maleic anhydride
[Ce]
cerium
O=C1C=CC(=O)O1
maleic anhydride
CCCC
n-butane

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    Otroprepared

Procedimiento

The catalyst promoted with cerium (V:Ce atomic ratio=1:0.005) prepared and calcined as stated in Example 4 was used to oxidise n-butane to maleic anhydride under "fuel lean" conditions. The crystallite size of the catalyst precursor after ball milling was about 300 A. After 183 hours time on line with a feed concentration of n-butane of 1.5 mole % in air at a reactor temperature of 420° C. at a GHSV of 3100 hr-1 the catalyst gave a 49 mole % pass yield of maleic anhydride at an n-butane conversion of 89%.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US04222945uspto-grants-1980_09