Reacción #554599

Ecuación de reacción

boron boron tribromide

water

2-methoxytriphenylene

→

2-hydroxytriphenylene

Rendimiento 95.1%

Disolventes

methylene chloride

methylene chloride

Condiciones de reacción

Tratamiento posterior

1. 1
   Temperaturawhile increasing temperature of the reaction solution to room temperature
2. 2
   Filtraciónfollowed by filtration
3. 3
   LavadoThe resulting solid was washed with water and methanol

Procedimiento

Under an argon atmosphere, 13.9 g of 2-methoxytriphenylene was placed in a flask, and 300 mL of methylene chloride was added. The reaction solution was cooled to −78° C., and 54 mL of a solution of 1M boron boron tribromide in methylene chloride was dropwise added thereto. The reaction solution was stirred for 5 hours while increasing temperature of the reaction solution to room temperature. 100 mL of water was added to the reaction solution, followed by filtration. The resulting solid was washed with water and methanol to obtain 12.5 g (yield: 95%) of 2-hydroxytriphenylene.

Fuente