Reacción #54447

ord-4b0992e459a24daaa1b21148f6ab2d51

Ecuación de reacción

CCCCCCCCCCCCCCCCCC(=O)Cl
stearoyl chloride
ClCl
chlorine
O=S(=O)(O)Cl
ClSO3H
N#CC(C#N)=c1ccc(=C(C#N)C#N)cc1
TCNQ
→
CCCCCCCCCCCCCCCCC(Cl)C(=O)Cl
2-chlorostearoyl chloride

Reactantes

CCCCCCCCCCCCCCCCCC(=O)Cl
stearoyl chloride
ClCl
chlorine
O=S(=O)(O)Cl
ClSO3H
N#CC(C#N)=c1ccc(=C(C#N)C#N)cc1
TCNQ

Reactivos

Ninguno

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    workup.DISTILLATIONThe product is distilled

Procedimiento

Following the procedure of Example I, stearoyl chloride is reacted with chlorine in the presence of ClSO3H and TCNQ. The product is distilled to provide substantially pure 2-chlorostearoyl chloride.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US04148811uspto-grants-1979_04